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李长坤


1、基本信息
姓名:李长坤
职称:特别研究员
邮箱:chkli@sjtu.edu.cn

主页:scce.sjtu.edu.cn
通讯地址:上海市东川路800号化学化工学院B楼237

电话:021-54738144


2、教育经历
2000.09-2004.06:北京大学化学与分子工程学院,学士
2004.09-2010.07:北京大学化学与分子工程学院,博士,导师:王剑波教授、张艳教授

3、工作经历
2010.07-2012.09:日本京都大学工学院,博士后,导师:Masahiro Murakami 教授
2012.10-2016.02:德国弗莱堡大学化学系,博士后,导师:Bernhard Breit 教授
2016.03-至今:很很鲁很很鲁视在线视频|香蕉伊人不卡在线看|天天鲁啪视频在线,特别研究员

4、研究方向
(1) 金属有机化学
(2) 不对称催化
(3) 有机合成

5、荣誉奖励

2020 Thieme Chemistry Journal Award

2013 德国洪堡基金会奖学金
2011 日本学术振兴会(JSPS)奖学金 


6、发表文章 


(9) Rh(I)-Catalyzed Regio- and Enantioselective Allylic Alkylation of Meldrum's Acid 

Min Liu, Haiying Zhao,* Changkun Li.*

Chin. Chem. Lett. 2020, 31, doi.org/10.1016/j.cclet.2020.04.009.



(8) Cobalt-Catalyzed Regio- and Enantioselective Allylic Alkylation of Malononitriles

Samir Ghorai, Sajid Ur Rehman, Wen-Bin Xu, Wen-Yu Huang, Changkun Li.*

Org. Lett. 2020, 22, 3519-3523.

 


(7) Rh(I)/Bisoxazolinephosphine-Catalyzed Regio- and Enantioselective Allylic Substitutions

Wen-Bin Xu, Samir Ghorai, Wenyu Huang, Changkun Li.*

ACS. Catal. 2020, 10, 4491-4496. 



(6)  Pd-Catalyzed Enantioselective Synthesis of 2-Methyl-3-methyleneindoline. 

Chun-Hua Lu, Sima, Darvishi, Vahid, Khakyzadeh, Changkun Li.*

Chin. Chem. Lett. 2020, 31, doi.org/10.1016/j.cclet.2020.02.056. 


(5) Cobalt-Catalyzed gem-Cross-Dimerization of Terminal Alkynes.

Jia-Feng Chen, Changkun Li.*

ACS. Catal. 2020, 10, 3881-3889. 


(4) Cobalt-Catalyzed Regio- and Enantioselective Allylic Amination.

Samir Ghorai, Sahadev Shrihari Chirke, Wen-Bin Xu, Jia-Feng Chen, Changkun Li.*

J. Am. Chem. Soc. 2019, 141, 1143011434.



(3) Construction of Vicinal Quaternary Carbon Centers via Cobalt-Catalyzed     Asymmetric Reverse Prenylation.

Minghe Sun#, Jia-Feng Chen#, Shufeng Chen, Changkun Li.*

Org. Lett. 2019, 21, 1278-1281. (#, equal contribution)

 


(2) Enol Ester Synthesis via Cobalt-Catalyzed Regio- and Stereoselective

Addition of Carboxylic Acids to Alkynes.

Jia-Feng Chen, Changkun Li.*

Org. Lett. 2018, 20, 6719-6724.

 


(1)  Rh(I)-Catalyzed Carbonylative [3+1] Constrcution of Cyclobutenones

via C-C s-Bond Activation of Cyclopropenes.

Wen-Bin Xu, Changkun Li,* and Jianbo Wang

Chem. Eur. J. 2018, 24, 15786-15790.

 


2016年之前:

(1) Rhodium-Catalyzed Chemo-, Regio-, and Enantioselective Addition of 2-Pyridones to Terminal Allenes
Changkun Li, Matthias Khny and Bernhard Breit* Angew. Chem., Int. Ed. 2014, 53, 13780-13784.
(2) Rhodium-Catalyzed Chemo- and Regioselective Decarboxylative Addition of β-Ketoacids to Allenes: Efficient Construction of Tertiary and Quaternary Carbon Centers.
Changkun Li, and Bernhard Breit* J. Am. Chem. Soc. 2014, 136, 862-865.
(3) Pyridine-Directed Palladium-Catalyzed Phosphonation of C(sp2)-H Bonds
Changkun Li, Takaaki Yano, Naoki Ishida, and Masahiro Murakami* Angew. Chem., Int. Ed. 2013, 52, 9801-9804.
(4) Gold(I)-Catalyzed Cycloisomerization of Enynes Containing Cyclopropenes
Changkun Li, Yi Zeng, Hang Zhang, Jiajie Feng, Yan Zhang, Jianbo Wang* Angew. Chem., Int. Ed. 2010, 49, 6413-6417.
7、其他
欢迎对有机合成、金属有机和不对称催化等方向感兴趣的本科生、硕士生、博士生和博士后加入本课题组。

 

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地址:上海市东川路800号 200240

电话:021-54742893

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